四氮雜卟啉
四氮雜卟啉
IUPAC名Porphyrazine
別名
5,10,15,20-Tetraazaporphine; Tetraazaporphine; Tetraazaporphyrin; Tetrazaporphin
識別
CAS號
500-77-6 Y
PubChem
5014177
ChemSpider
24785772
SMILES
C1=CC3=NC1=NC5=CC=C(N=C2C=CC(=N2)N=C4C=CC(=N3)N4)N5
性質
化學式
C16H10N8
摩爾質量
314.3 g·mol−1
若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。
四氮雜卟啉是一種四吡咯基大環化合物，化學式為C16H10N8，其結構與卟啉或酞菁相似。Patrick Linstead最早開始了四氮雜卟啉的研究。[1]它的一個結構拓展是四吡嗪並四氮雜卟啉。[2]
它在紫外、可見光和近紅外光譜範圍內的強烈電子吸收，[3]Soret帶位於300 - 400 nm，Q帶在>600 nm處。[4]
參考文獻[編輯]
^ Cook, A. H.; Linstead, R. P., "Phthalocyanines. XI. The preparation of octaphenylporphyrazines from diphenylmaleinitrile." J. Chem. Soc. 1937, 929-933.DOI: 10.1039/JR9370000929
^ Donzello, Maria Pia; Ercolani, Claudio; Novakova, Veronika; Zimcik, Petr; Stuzhin, Pavel A. Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information. Coordination Chemistry Reviews. 2016-02-15, 309: 107–179. ISSN 0010-8545. doi:10.1016/j.ccr.2015.09.006.
^ Kobayashi, N. and H. Konami (1996) Molecular orbitals and electronic spectra of phthalocyanine analogues. In Phthalocyanines: Properties and Applications, Vol. 4 (Edited by C. C. Leznoff and A. B. P. Lever), pp. 343–404. VCH Publishers, Inc., New York.
^ Linstead, R. P.; Whalley, M., Conjugated Macrocycles. Part XXI Tetrazaporphin and its Metallic Derivatives. J. Chem. Soc. 1952, 4839-4844.